The
separation of CO2 from flue gases has greatly enhanced greenhouse effect.
Presence of gases particularly CO2 continuously increased earth temperature.
Its decrease greatly reduces global warming. CO2 is mainly found in fuel gasfrom combustion of fossil fuel, coal gasification and natural gas streams. CO2
gas due to its acidity reduces the calorific value of gas streams, makes it
corrosive, and so causes problems for gas compression and transportation.
Natural gas in pipelines contains less than 2% CO2 to avoid corrosiveness. Keeping
in view of this problem there are various methods invented to reduce CO2 in gas
streams before it is compressed. On the other hand CO2 can be used for enhanced
oil recovery where liquid CO2 is injected into the reservoir to increase the
flow of oil, therefore increase the productivity of reservoir. CO2 level in
atmosphere can be reduced by injecting it deep into ocean or depleted well so
economically and technically sound methods are needed for CO2 removal and
capture.
Conventional
methods for CO2 separation include chemical absorption with a monoethanolamine(MEA) solvent, cryogenic fractionation, and adsorption using molecular sieves.
Although these methods are mature but their equipment complexity, energy
consumption and capital cost is high.
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